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Hydroarylation of N ‐Allenyl Derivatives Catalyzed by Copper

Abstract : An additive-free copper catalytic system was used to perform the addition of (hetero)aryl nucleophiles to N-allenyl derivatives. This intermolecular C–C bond formation occurs with both complete regio- and stereoselectivity to afford the linear (E) allylic product with moderate to excellent yields. This atom economical method is the first example of hydroarylation of allenes catalyzed by copper.
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Contributor : Marc Taillefer Connect in order to contact the contributor
Submitted on : Friday, November 26, 2021 - 11:37:11 AM
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Racha Abed Ali Abdine, Lucas Pagès, Marc Taillefer, Florian Monnier. Hydroarylation of N ‐Allenyl Derivatives Catalyzed by Copper. European Journal of Organic Chemistry, Wiley-VCH Verlag, 2020, 2020 (48), pp.7466-7469. ⟨10.1002/ejoc.202001333⟩. ⟨hal-03450694⟩



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