H. Y. Tian, Z. H. Tang, X. L. Zhuang, X. S. Chen, and X. B. Jing, Biodegradable synthetic polymers: Preparation, functionalization and biomedical application, Progress in Polymer Science, vol.37, issue.2, pp.237-280, 2011.
DOI : 10.1016/j.progpolymsci.2011.06.004

K. F. Pack, A. M. Klibanov, and R. Langer, Visual evidence of acidic environment within degrading poly(lactic-co-glycolic acid) (PLGA) microspheres, Pharmaceutical Research, pp.17-100, 2000.

R. D. Santis, A. Russo, A. Gloria, U. D-'amora, T. Russo et al., Towards the Design of 3D Fiber-Deposited Poly( -caprolactone)/Iron-Doped Hydroxyapatite Nanocomposite Magnetic Scaffolds for Bone Regeneration, Journal of Biomedical Nanotechnology, vol.11, issue.7, pp.1236-1246, 2015.
DOI : 10.1166/jbn.2015.2065

Z. W. Huang, V. Laurent, G. Chetouani, J. Y. Ljubimov, E. Holler et al., New functional degradable and bio-compatible nanoparticles based on poly(malic acid) derivatives for site-specific anti-cancer drug delivery, International Journal of Pharmaceutics, vol.423, issue.1, pp.84-92, 2012.
DOI : 10.1016/j.ijpharm.2011.04.035

URL : https://hal.archives-ouvertes.fr/inserm-00864846

J. Y. Ljubimova, J. Portilla-arias, R. Patil, H. Ding, S. Inoue et al., Toxicity and efficacy evaluation of multiple targeted polymalic acid conjugates for triple-negative breast cancer treatment, Journal of Drug Targeting, vol.113, issue.10, pp.956-967, 2013.
DOI : 10.1097/PPO.0b013e318074d80a

P. Loyer and S. Cammas-marion, Natural and synthetic poly(malic acid)-based derivates: a family of versatile biopolymers for the design of drug nanocarriers, Journal of Drug Targeting, vol.20, issue.7, pp.556-575, 2014.
DOI : 10.1016/j.ejmech.2008.04.021

URL : https://hal.archives-ouvertes.fr/hal-01063205

A. Lanz-landázuri, A. Martínez-de-ilarduya, M. García-alvarez, and S. N. Muñoz-guerra, Poly(?.L-malic acid)/doxorubicin ionic complex: a pH-dependent delivery system, Reactive and Functional Polymers, pp.81-126, 2014.

Y. Qiao, X. Duan, L. Fan, W. Li, H. Wu et al., Synthesis of controlled molecular weight poly (??-malic acid) and conjugation with HCPT as a polymeric drug carrier, Journal of Polymer Research, vol.99, issue.4, pp.1-9, 2014.
DOI : 10.1007/s10965-014-0397-4

P. Mcdonald, J. Lyons, L. Geever, and C. Higginbotham, In vitro degradation and drug release from polymer blends based on poly(dl-lactide), poly(l-lactide-glycolide) and poly(??-caprolactone), Journal of Materials Science, vol.2, issue.5, pp.1284-1292, 2009.
DOI : 10.1007/s10853-009-4080-9

S. T. Schmitz-hertzberg, W. C. Mak, K. K. Lai, C. Teller, and F. F. Bier, Multifactorial design of poly(d.l-lactic-co-glycolic acid) capsules with various release properties for differently sized filling agents, Journal of Applied Polymer Science, vol.130, issue.4219, 2013.

L. Wang, X. Jia, Y. Chen, Y. Che, and Z. Yuan, Synthesis, degradability, and cell affinity of poly (DL-lactide-co-RS-hydroxyethyl-beta-malolactonate), Journal Of Biomedical Materials Research Part A, vol.87, pp.459-469, 2008.

K. L. Lai, B. He, and Z. W. Gu, PREPARATION AND CELL COMPATIBILITY OF FUNCTIONALIZED BIODEGRADABLE POLY(DL-LACTIDE-co-RS-??-MALIC ACID), Chinese Journal of Polymer Science, vol.26, issue.02, pp.177-186, 2008.
DOI : 10.1142/S0256767908002819

Y. Liu, W. Wang, J. Wang, Y. Wang, Z. Yuan et al., Blood compatibility evaluation of poly(d.l-lactide-co-beta-malic acid) modified with the GRGDS sequence, Colloids and Surfaces B: Biointerfaces, vol.75, issue.370, 2010.

J. Qian, W. Xu, W. Zhang, and X. Jin, Preparation and characterization of biomorphic poly(l-lactide-co-??-malic acid) scaffolds, Materials Letters, vol.124, p.313, 2014.
DOI : 10.1016/j.matlet.2014.03.109

Y. Zhang, C. Ni, G. Shi, J. Wang, M. Zhang et al., The polyion complex nano-prodrug of doxorubicin (DOX) with poly(lactic acid-co-malic acid)-block-polyethylene glycol: preparation and drug controlled release, Medicinal Chemistry Research, vol.12, issue.169, pp.1189-1195, 2015.
DOI : 10.1007/s00044-014-1206-7

H. Ding, G. Helguera, J. A. Rodriguez, J. Markman, R. Luria-perez et al., Polymalic acid nanobioconjugate for simultaneous immunostimulation and inhibition of tumor growth in HER2/neu-positive breast cancer, Journal of Controlled Release, vol.171, issue.3, pp.322-329, 2013.
DOI : 10.1016/j.jconrel.2013.06.001

B. Lee, M. Vert, and E. Holler, Water-soluble Aliphatic Polyesters: Poly(Malic Acid)s, Biopolymers Online, 2005.

B. Gasslmaier, Synthetic substrates and inhibitors of ??-poly(L-malate)-hydrolase (polymalatase), European Journal of Biochemistry, vol.261, issue.Suppl. 1, 2000.
DOI : 10.1046/j.1432-1327.2000.01573.x

B. He, J. Bei, and S. Wang, Morphology and degradation of biodegradable poly(L-lactideco-?-malic acid), Polymers for Advanced Technologies, pp.14-645, 2003.

L. K. Sarah, X. T. Vinh, K. Cathrin, P. B. Anaïs, and P. D. Andrew, Synthetic strategies, sustainability and biological applications of malic acid-based polymers, pp.107-122, 2014.

S. Benni, T. Avramoglou, H. Hlawaty, and L. Mora, Dynamic Contact Angle Analysis of Protein Adsorption on Polysaccharide Multilayer???s Films for Biomaterial Reendothelialization, BioMed Research International, vol.24, issue.1, pp.2014-679031, 2014.
DOI : 10.1016/j.msec.2005.10.049

D. Bonn, J. Eggers, J. Indekeu, J. Meunier, and E. Rolley, Wetting and spreading, Reviews of Modern Physics, vol.81, issue.2, pp.739-805, 2009.
DOI : 10.1103/RevModPhys.81.739

E. H. Sohn, B. G. Kim, J. S. Chung, H. Kang, and J. C. Lee, Wettability of the morphologically and compositionally varied surfaces prepared from blends of well ordered comblike polymer and polystyrene, Journal of Colloid and Interface Science, vol.354, issue.650, 2011.

T. T. Chau, W. J. Bruckard, P. T. Koh, and A. V. Nguyen, A review of factors that affect contact angle and implications for flotation practice, Advances in Colloid and Interface Science, vol.150, issue.2, pp.106-115, 2009.
DOI : 10.1016/j.cis.2009.07.003

R. , D. Mundo, F. Bottiglione, and G. Carbone, Cassie state robustness of plasma generated randomly nano-rough surfaces, Applied Surface Science, vol.316, pp.324-332, 2014.

E. Bormashenko, Why does the Cassie???Baxter equation apply?, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.324, issue.1-3, pp.47-50, 2008.
DOI : 10.1016/j.colsurfa.2008.03.025

]. L. Ponsonnet, K. Reybier, N. Jaffrezic, V. Comte, C. Lagneau et al., Relationship between surface properties (roughness, wettability) of titanium and titanium alloys and cell behaviour, Materials Science and Engineering: C, vol.23, issue.4, pp.551-560, 2003.
DOI : 10.1016/S0928-4931(03)00033-X

C. Barbaud, S. Cammas-marion, and P. Guerin, Poly(??-malic acid) derivatives with non-charged hydrophilic lateral groups: synthesis and characterization, Polymer Bulletin, vol.43, issue.4-5, pp.297-304, 1999.
DOI : 10.1007/s002890050614

C. Barbaud, F. Faÿ, F. Abdillah, S. Randriamahefa, and P. Guérin, Synthesis of new homopolyester and copolyesters by anionic ring-opening polymerization of ?,??,?trisubstituted ?-lactones, Macromolecular Chemistry and Physics, vol.205, 0199.

F. Ouhib, S. Randriamahefa, P. Guerin, and C. Barbaud, Synthesis of new statistical and block co-polyesters by ROP of <I>??</I>,<I>??</I>,<I>??</I>-trisubstituted <I>??</I>-lactones and their characterizations, Designed Monomers & Polymers, vol.8, issue.1, pp.25-35, 2005.
DOI : 10.1163/1568555053084221

C. Barbaud, F. Abdillah, F. Faÿ, M. Guerrouache, and P. Guérin, Synthesis of new alpha,alpha,beta-trisubstituted beta-lactones as monomers for hydrolyzable polyesters, Designed Monomers and Polymers, vol.6, issue.353, 2003.

F. E. Kohn, The ring-opening polymerization of D,L-lactide in the melt initiated with tetraphenyltin, Journal of Applied Polymer Science, vol.29, issue.12, pp.4265-4277, 1984.
DOI : 10.1002/app.1984.070291255

J. Van-oss and . Carel, Forces interfaciales en milieux, pp.14-402, 1996.

Y. Huang, H. C. Ng, X. W. Ng, and V. Subbu, Drug-eluting biostable and erodible stents, Journal of Controlled Release, vol.193, issue.188, 2014.
DOI : 10.1016/j.jconrel.2014.05.011

F. M. Zambaux, F. Bonneaux, R. Gref, E. Dellacherie, C. Vigneron et al., Effect of MPEO Content on Some of Their Surface Properties, pp.109-115, 1999.

L. Xiao, Poly(Lactic Acid)-Based Biomaterials: Synthesis, Modification and Applications, pp.248-282, 2012.
DOI : 10.5772/23927

M. Persson, Effect of bioactive extruded PLA/HA composite films on focal adhesion formation of preosteoblastic cells, Colloids and Surfaces B: Biointerfaces, vol.121, issue.409, 2014.
DOI : 10.1016/j.colsurfb.2014.06.029

Y. Wang and J. Cai, Enhanced cell affinity of poly(l-lactic acid) modified by base hydrolysis: Wettability and surface roughness at nanometer scale, Current Applied Physics, vol.7, issue.108, 2007.
DOI : 10.1016/j.cap.2006.11.027

I. M. De-rosa, Poly(lactic acid)/Phormium tenax composites: Morphology and thermo-mechanical behavior, Polymer Composites, vol.63, issue.9, pp.32-1362, 2011.
DOI : 10.1002/pc.21159

J. Wang, Preparation and pH controlled release of polyelectrolyte complex of poly(l-malic acid-co-d,l-lactic acid) and chitosan, Colloids and Surfaces B: Biointerfaces, vol.115, p.275, 2014.
DOI : 10.1016/j.colsurfb.2013.12.018

M. A. Leboucherdurand, V. Langlois, and P. Guerin, 4-carboxy-2-oxetanone as a new chiral precursor in the preparation of functionalized racemic or optically active poly(malic acid) derivatives, Polym. Bull, pp.36-71, 1996.

S. Cammas, M. M. Bear, L. Moine, R. Escalup, G. Ponchel et al., Polymers of malic acid and 3-alkylmalic acid as synthetic PHAs in the design of biocompatible hydrolyzable devices, International Journal of Biological Macromolecules, vol.25, issue.1-3, pp.273-282, 1999.
DOI : 10.1016/S0141-8130(99)00042-2

A. W. Gaydos and . Neumann, Line tension in multiphase equilibrium systems, Applied Surface Thermodynamics, pp.169-238, 1996.

E. I. Vargha-butler, E. Kiss, C. N. Lam, Z. Keresztes, E. Kalman et al., Wettability of biodegradable surfaces, Wettability of biodegradable surfaces, pp.1160-1168, 2001.
DOI : 10.1007/s003960100549

D. Cohn, H. Younes, P. /. Biodegradable, . Pla, and . Copolymers, Biodegradable PEO/PLA block copolymers, Journal of Biomedical Materials Research, vol.6, issue.11, p.993, 1988.
DOI : 10.1002/jbm.820221104

K. Spiridon, A. M. Leluk, R. N. Resmerita, and . Darie, Evaluation of PLA???lignin bioplastics properties before and after accelerated weathering, Composites Part B: Engineering, vol.69, pp.342-349, 2015.
DOI : 10.1016/j.compositesb.2014.10.006

I. Chemistry, Operating manual DataPhysics OCA, DataPhysics Instruments GmbH, pp.1-4, 2002.

Y. Huang, Drug Eluting Stents: Anti-inflammatory Approach to Prevent Restenosis After Stent Implantation, 2003.